Optical Rotation Values of Carbohydrates
Table: Optical Rotation Values. Optical rotation measures the degree to which a substance rotates plane-polarized light, expressed in degrees. It is a key property of chiral molecules like carbohydrates, influenced by their molecular structure, concentration, and solvent. Positive values indicate dextrorotation (clockwise rotation), while negative values indicate levorotation (counterclockwise rotation). This property is critical for characterizing the structural and stereochemical properties of carbohydrates and polysaccharides in applications such as biochemistry, food science, and pharmaceuticals.
Substance | Solvent | Optical Rotation 1 (degrees) | Optical Rotation 2 (degrees) | Ref (DOI) |
---|---|---|---|---|
Methyl 2-methyl-β-glucoside | Cupra Water | +985 | -69 | 10.1016/S0021-9258(18)71941-8 |
Methyl 3-methyl-β-glucoside | Cupra Water | -86 | -46 | 10.1016/S0021-9258(18)71941-8 |
Methyl 4-methyl-β-glucoside | Cupra Water | -1008 | -36 | 10.1016/S0021-9258(18)71941-8 |
Methyl 6-methyl-β-glucoside | Cupra Water | +161 | -48 | 10.1016/S0021-9258(18)71941-8 |
Cellulose | Cupra | -1200 | -194,400 | 10.1016/S0021-9258(18)71941-8 |
Cellulose | Water-Triton B (1:1) | -46 | -7,500 | 10.1016/S0021-9258(18)71941-8 |
Starch (soluble) | Cupra | -715 | -115,800 | 10.1016/S0021-9258(18)71941-8 |
Starch (soluble) | Water | +375 | +60,800 | 10.1016/S0021-9258(18)71941-8 |
Glycogen | Cupra | -597 | -96,700 | 10.1016/S0021-9258(18)71941-8 |
Glycogen | Water containing NaCl | +366 | +59,300 | 10.1016/S0021-9258(18)71941-8 |
Laminarin | Cupra | +34 | +5,500 | 10.1016/S0021-9258(18)71941-8 |
Laminarin | Water | -29 | -4,700 | 10.1016/S0021-9258(18)71941-8 |
Polysaccharide from Phytomonas tumefaciens | Cupra | +960 | +155,500 | 10.1016/S0021-9258(18)71941-8 |
Polysaccharide from Phytomonas tumefaciens | Water | -23 | -3,700 | 10.1016/S0021-9258(18)71941-8 |
Dextran from Leuconostoc dextranicum | Cupra | -128 | -20,700 | 10.1016/S0021-9258(18)71941-8 |
Dextran from Leuconostoc dextranicum | Water | +297 | +48,100 | 10.1016/S0021-9258(18)71941-8 |