Optical Rotation Values of Carbohydrates

Table: Glass Transition Temperature (Tg). The glass transition temperature (Tg) is the temperature range at which a carbohydrate or polysaccharide transitions from a hard, glassy state to a more flexible, rubbery state. Measured in degrees Celsius (°C), Tg is a critical property influencing the physical stability, texture, and processing behavior of carbohydrates in applications such as food science, pharmaceuticals, and material design. Variations in Tg depend on molecular structure, composition, and environmental factors like moisture content.

Carbohydrate Type Glass Transition Temperature (Tg, °C) Ref (DOI)
Sucrose 62–70 10.1016/j.matdes.2019.108324
Maltose 87 10.1016/j.matdes.2019.108324
Maltitol 39 10.1016/j.matdes.2019.108324
Glucose 31 10.1016/j.matdes.2019.108324
Fructose 5–10 10.1016/j.matdes.2019.108324
Lactitol 52–58 10.1016/j.matdes.2019.108324
Sorbitol -9 10.1016/j.matdes.2019.108324
Erythritol -59.7 10.1016/j.matdes.2019.108324
Xylitol -29 10.1016/j.matdes.2019.108324
Mannitol 13 10.1016/j.matdes.2019.108324
Isomalt 63.6 10.1016/j.matdes.2019.108324
Trehalose 116.9 10.1021/jp002847k
Raffinose 112.6 10.1021/jp002847k
Lactose 112.3 10.1021/jp002847k
Cellobiose 108.1 10.1021/jp002847k
Melibiose 101.3 10.1021/jp002847k
Gentiobiose 100.8 10.1021/jp002847k
Lactulose 94.2 10.1021/jp002847k
Leucrose 89.5 10.1021/jp002847k
Turanose 88.2 10.1021/jp002847k
Palatinose 68.9 10.1021/jp002847k