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{
"count": 97,
"next": "http://glycodata.org/api/gdd/polymer-solubility/?format=api&page=3",
"previous": "http://glycodata.org/api/gdd/polymer-solubility/?format=api",
"results": [
{
"id": 21,
"polymer": "Cellulose acetate",
"solvent": "n-Hexane",
"concentration_mg_ml": "15",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "100",
"transmission_25C": "69",
"transmission_60C": "11",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=183); observed range 11-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in n-Hexane at 15 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 22,
"polymer": "Chitosan",
"solvent": "1,2,4-trichlorobenzene",
"concentration_mg_ml": "14.52",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "19",
"transmission_25C": "25",
"transmission_60C": "48",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.52 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.52 mg/mL polymer, Mn 15000 g/mol (Polysciences). Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=210); observed range 19-48 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in 1,2,4-trichlorobenzene at 14.52 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 23,
"polymer": "Chitosan",
"solvent": "1-Octanol",
"concentration_mg_ml": "15.09",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "1",
"transmission_25C": "1",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.09 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.09 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-1 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in 1-Octanol at 15.09 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 24,
"polymer": "Chitosan",
"solvent": "2,4,6-trimethylpyridine",
"concentration_mg_ml": "14.71",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "13",
"transmission_25C": "10",
"transmission_60C": "8",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.71 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.71 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=124); observed range 8-13 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in 2,4,6-trimethylpyridine at 14.71 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 25,
"polymer": "Chitosan",
"solvent": "Acetone",
"concentration_mg_ml": "15.13",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "2",
"transmission_25C": "2",
"transmission_60C": "2",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.13 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.13 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.5 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 2-2 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Acetone at 15.13 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 26,
"polymer": "Chitosan",
"solvent": "Acetonitrile",
"concentration_mg_ml": "15.32",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "1",
"transmission_25C": "1",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.32 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.32 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.5 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-1 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Acetonitrile at 15.32 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 27,
"polymer": "Chitosan",
"solvent": "Anisole",
"concentration_mg_ml": "5.02",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "100",
"transmission_25C": "83",
"transmission_60C": "65",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "5.02 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 5.02 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=158); observed range 65-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Anisole at 5.02 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 28,
"polymer": "Chitosan",
"solvent": "Anisole",
"concentration_mg_ml": "50.01",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "9",
"transmission_25C": "5",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "50.01 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 50.01 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-9 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Anisole at 50.01 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 29,
"polymer": "Chitosan",
"solvent": "Benzyl alcohol",
"concentration_mg_ml": "14.49",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "49",
"transmission_25C": "49",
"transmission_60C": "32",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.49 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.49 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=210); observed range 32-53 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Benzyl alcohol at 14.49 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 30,
"polymer": "Chitosan",
"solvent": "Chlorobenzene",
"concentration_mg_ml": "4.99",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "98",
"transmission_25C": "84",
"transmission_60C": "65",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "4.99 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 4.99 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=157); observed range 64-98 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Chlorobenzene at 4.99 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 31,
"polymer": "Chitosan",
"solvent": "Chlorobenzene",
"concentration_mg_ml": "50.02",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "15",
"transmission_25C": "10",
"transmission_60C": "2",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "50.02 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 50.02 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=102); observed range 2-68 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Chlorobenzene at 50.02 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 32,
"polymer": "Chitosan",
"solvent": "Chloroform",
"concentration_mg_ml": "15.04",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "5",
"transmission_25C": "4",
"transmission_60C": "2",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.04 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.04 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 2-5 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Chloroform at 15.04 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 33,
"polymer": "Chitosan",
"solvent": "Cyclohexane",
"concentration_mg_ml": "15.03",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "3",
"transmission_25C": "3",
"transmission_60C": "3",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.03 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.03 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.5 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 3-3 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Cyclohexane at 15.03 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 34,
"polymer": "Chitosan",
"solvent": "DMF",
"concentration_mg_ml": "15.17",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "2",
"transmission_25C": "1",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.17 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.17 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-2 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in DMF at 15.17 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 35,
"polymer": "Chitosan",
"solvent": "DMSO",
"concentration_mg_ml": "14.96",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "0",
"transmission_25C": "4",
"transmission_60C": "4",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.96 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.96 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.9 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 0-5 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in DMSO at 14.96 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 36,
"polymer": "Chitosan",
"solvent": "Diethyl ether",
"concentration_mg_ml": "5.03",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "22",
"transmission_25C": "24",
"transmission_60C": "31",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "5.03 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 5.03 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=210); observed range 22-32 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Diethyl ether at 5.03 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 37,
"polymer": "Chitosan",
"solvent": "Diethyl ether",
"concentration_mg_ml": "50.14",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "0",
"transmission_25C": "0",
"transmission_60C": "0",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "50.14 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 50.14 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 0-0 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Diethyl ether at 50.14 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 38,
"polymer": "Chitosan",
"solvent": "Ethyl acetate",
"concentration_mg_ml": "14.98",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "1",
"transmission_25C": "1",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.98 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.98 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 99.5 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-1 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Ethyl acetate at 14.98 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 39,
"polymer": "Chitosan",
"solvent": "Ethyl lactate",
"concentration_mg_ml": "5.22",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Partially soluble",
"transmission_10C": "21",
"transmission_25C": "22",
"transmission_60C": "23",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "5.22 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 5.22 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 98 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=210); observed range 21-23 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Ethyl lactate at 5.22 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 40,
"polymer": "Chitosan",
"solvent": "Ethyl lactate",
"concentration_mg_ml": "50.13",
"molecular_weight": "15000",
"supplier": "Polysciences",
"solubility_class": "Insoluble",
"transmission_10C": "0",
"transmission_25C": "0",
"transmission_60C": "0",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "50.13 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 50.13 mg/mL polymer, Mn 15000 g/mol (Polysciences); solvent purity 98 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 0-0 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Chitosan in Ethyl lactate at 50.13 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
}
]
}