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{
"count": 97,
"next": "http://glycodata.org/api/gdd/polymer-solubility/?format=api&page=2",
"previous": null,
"results": [
{
"id": 1,
"polymer": "Cellulose acetate",
"solvent": "1,4-dioxane",
"concentration_mg_ml": "15.01",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "56",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "16",
"method": "Experiment",
"conditions": "15.01 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.01 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=48); observed range 23-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in 1,4-dioxane at 15.01 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Approx. cloud point on cooling ~16 °C. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 2,
"polymer": "Cellulose acetate",
"solvent": "1-Octanol",
"concentration_mg_ml": "14.98",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "48",
"transmission_25C": "43",
"transmission_60C": "8",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.98 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.98 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=186); observed range 8-58 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in 1-Octanol at 14.98 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 3,
"polymer": "Cellulose acetate",
"solvent": "2,4,6-trimethylpyridine",
"concentration_mg_ml": "15.04",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "76",
"transmission_25C": "80",
"transmission_60C": "58",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.04 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.04 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=209); observed range 38-95 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in 2,4,6-trimethylpyridine at 15.04 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 4,
"polymer": "Cellulose acetate",
"solvent": "Acetonitrile",
"concentration_mg_ml": "14.96",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.96 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.96 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.5 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 100-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Acetonitrile at 14.96 mg/mL is soluble: clear (T > 85 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 5,
"polymer": "Cellulose acetate",
"solvent": "Anisole",
"concentration_mg_ml": "14.94",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.94 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.94 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=52); observed range 83-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Anisole at 14.94 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 6,
"polymer": "Cellulose acetate",
"solvent": "Benzene",
"concentration_mg_ml": "14.91",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "59",
"transmission_25C": "69",
"transmission_60C": "78",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.91 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.91 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=146); observed range 58-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Benzene at 14.91 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 7,
"polymer": "Cellulose acetate",
"solvent": "Benzyl alcohol",
"concentration_mg_ml": "15.04",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "94",
"transmission_25C": "64",
"transmission_60C": "100",
"cloud_point_C": "37",
"method": "Experiment",
"conditions": "15.04 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.04 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=72); observed range 52-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Benzyl alcohol at 15.04 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Approx. cloud point on cooling ~37 °C. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 8,
"polymer": "Cellulose acetate",
"solvent": "Chlorobenzene",
"concentration_mg_ml": "14.97",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "17",
"transmission_25C": "25",
"transmission_60C": "65",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.97 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.97 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=211); observed range 16-65 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Chlorobenzene at 14.97 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 9,
"polymer": "Cellulose acetate",
"solvent": "Cyclohexanone",
"concentration_mg_ml": "14.4",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "",
"transmission_25C": "",
"transmission_60C": "",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.4 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.4 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=2); observed range 74-74 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Cyclohexanone at 14.4 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 10,
"polymer": "Cellulose acetate",
"solvent": "Cyclopentanone",
"concentration_mg_ml": "15.02",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.02 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.02 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 100-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Cyclopentanone at 15.02 mg/mL is soluble: clear (T > 85 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 11,
"polymer": "Cellulose acetate",
"solvent": "DMF",
"concentration_mg_ml": "15.14",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.14 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.14 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 100-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in DMF at 15.14 mg/mL is soluble: clear (T > 85 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 12,
"polymer": "Cellulose acetate",
"solvent": "DMSO",
"concentration_mg_ml": "14.92",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "0",
"transmission_25C": "99",
"transmission_60C": "100",
"cloud_point_C": "19",
"method": "Experiment",
"conditions": "14.92 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.92 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.9 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=46); observed range 0-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in DMSO at 14.92 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Approx. cloud point on cooling ~19 °C. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 13,
"polymer": "Cellulose acetate",
"solvent": "Diethyl ether",
"concentration_mg_ml": "14.92",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Insoluble",
"transmission_10C": "1",
"transmission_25C": "1",
"transmission_60C": "3",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.92 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.92 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.8 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 1-3 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Diethyl ether at 14.92 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 14,
"polymer": "Cellulose acetate",
"solvent": "Ethanol",
"concentration_mg_ml": "14.92",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "1",
"transmission_25C": "1",
"transmission_60C": "1",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.92 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.92 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 90 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=52); observed range 1-30 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Ethanol at 14.92 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 15,
"polymer": "Cellulose acetate",
"solvent": "Ethyl lactate",
"concentration_mg_ml": "15.06",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "26",
"method": "Experiment",
"conditions": "15.06 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.06 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 98 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=61); observed range 35-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Ethyl lactate at 15.06 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Approx. cloud point on cooling ~26 °C. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 16,
"polymer": "Cellulose acetate",
"solvent": "Heptane",
"concentration_mg_ml": "15",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "99",
"transmission_25C": "94",
"transmission_60C": "66",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=140); observed range 62-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Heptane at 15 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 17,
"polymer": "Cellulose acetate",
"solvent": "Isobutyl acetate",
"concentration_mg_ml": "14.98",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Insoluble",
"transmission_10C": "6",
"transmission_25C": "6",
"transmission_60C": "6",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.98 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.98 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=51); observed range 6-6 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Isobutyl acetate at 14.98 mg/mL is insoluble: turbid (T < 10 %) over the whole 10-60 °C cooling ramp. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 18,
"polymer": "Cellulose acetate",
"solvent": "Petroleum ether",
"concentration_mg_ml": "15.03",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "49",
"transmission_25C": "42",
"transmission_60C": "41",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.03 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.03 mg/mL polymer, Mn 50000 g/mol (Sigma). Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=210); observed range 35-54 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Petroleum ether at 15.03 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 19,
"polymer": "Cellulose acetate",
"solvent": "Pyridine",
"concentration_mg_ml": "15.36",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "100",
"transmission_25C": "100",
"transmission_60C": "100",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "15.36 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 15.36 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=52); observed range 81-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Pyridine at 15.36 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
},
{
"id": 20,
"polymer": "Cellulose acetate",
"solvent": "Toluene",
"concentration_mg_ml": "14.9",
"molecular_weight": "50000",
"supplier": "Sigma",
"solubility_class": "Partially soluble",
"transmission_10C": "80",
"transmission_25C": "70",
"transmission_60C": "73",
"cloud_point_C": "",
"method": "Experiment",
"conditions": "14.9 mg/mL, 10-60 °C, 0.5 °C/min",
"conditions_detail": "Crystal16 turbidity (645 nm), cooling ramp 60 to 10 °C at 0.5 °C/min after two heat/cool cycles; holds 120 min at 10 °C and 60 min at 60 and 25 °C; stirring 900 rpm. Sample: 14.9 mg/mL polymer, Mn 50000 g/mol (Sigma); solvent purity 99.9 %. Transmission binned per 1 °C (median of Savitzky-Golay filtered cooling-phase points, n=150); observed range 58-100 %. Class thresholds from the source paper: insoluble <10 %, soluble >85 %, partial 10-85 %. Nonequilibrium (0.5 °C/min).",
"doi": "10.1021/acs.jpcb.4c06500",
"comments": "Cellulose acetate in Toluene at 14.9 mg/mL is partially soluble: transmission between 10 and 85 % at some temperature on cooling. Class refers to nonequilibrium behaviour during the cooling ramp, not thermodynamic solubility. Data: Amrihesari et al., J. Phys. Chem. B 2024 (github.com/mona2442/Polymer-Solubility-Data_Crystal16)."
}
]
}