{"count":839,"next":"http://glycodata.org/api/gdd/glyco-properties/?format=json&page=27","previous":"http://glycodata.org/api/gdd/glyco-properties/?format=json&page=25","results":[{"id":501,"dataset":"cellulose","entity":"SigmaCell 50 cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"56.1","unit":"%","value_reported":"56.1","unit_reported":"%","method":"Experiment","method_detail":"13C CP/MAS NMR, C4 peak separation","conditions":"13C CP/MAS NMR, C4 peak separation","conditions_detail":"13C CP/MAS NMR, C4 peak separation | measurement: NMR C4 peak separation | allomorph: I | source: SigmaCell 50 (commercial cellulose)","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"SigmaCell 50 ... NMR C4 peak separation 56.1%\"  — Same SigmaCell 50 sample; NMR vs 91.2% by peak height.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":502,"dataset":"cellulose","entity":"SigmaCell 20 cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"84.8","unit":"%","value_reported":"84.8","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: SigmaCell 20 (commercial cellulose)","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"SigmaCell 20 ... XRD peak height 84.8%\"  — Table 2.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":503,"dataset":"cellulose","entity":"SigmaCell 20 cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"52.6","unit":"%","value_reported":"52.6","unit_reported":"%","method":"Experiment","method_detail":"13C CP/MAS NMR, C4 peak separation","conditions":"13C CP/MAS NMR, C4 peak separation","conditions_detail":"13C CP/MAS NMR, C4 peak separation | measurement: NMR C4 peak separation | allomorph: I | source: SigmaCell 20 (commercial cellulose)","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"SigmaCell 20 ... NMR C4 peak separation 52.6%\"  — Same SigmaCell 20 sample by NMR.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":504,"dataset":"cellulose","entity":"Fluka cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"82.9","unit":"%","value_reported":"82.9","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: Fluka cellulose (commercial)","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"Fluka cellulose ... XRD peak height 82.9%\"  — Table 2; NMR value for same sample = 48.6%.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":505,"dataset":"cellulose","entity":"Sigma alpha-cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"78.0","unit":"%","value_reported":"78.0","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: Sigma alpha-cellulose","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"Sigma alpha-cellulose ... XRD peak height 78.0%\"  — Table 2; NMR value for same sample = 41.5% (largest method spread).  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":506,"dataset":"cellulose","entity":"Sigma alpha-cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"41.5","unit":"%","value_reported":"41.5","unit_reported":"%","method":"Experiment","method_detail":"13C CP/MAS NMR, C4 peak separation","conditions":"13C CP/MAS NMR, C4 peak separation","conditions_detail":"13C CP/MAS NMR, C4 peak separation | measurement: NMR C4 peak separation | allomorph: I | source: Sigma alpha-cellulose","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"Sigma alpha-cellulose ... NMR C4 peak separation 41.5%\"  — Lowest NMR value among the eight samples.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":507,"dataset":"cellulose","entity":"SolkaFloc cellulose","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"78.3","unit":"%","value_reported":"78.3","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: SolkaFloc cellulose (wood pulp)","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"SolkaFloc cellulose ... XRD peak height 78.3%\"  — Table 2; NMR value for same sample = 43.9%.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":508,"dataset":"cellulose","entity":"Avicel PH-101 microcrystalline cellulose","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"53.0","unit":"%","value_reported":"39-67","unit_reported":"%","method":"Review","method_detail":"Multiple XRD analysis techniques (literature compilation by Thygesen et al.)","conditions":"Multiple XRD analysis techniques (literature compilation by Thygesen et al.)","conditions_detail":"Multiple XRD analysis techniques (literature compilation by Thygesen et al.) | measurement: XRD (various) | allomorph: I | source: Avicel PH-101","doi":"10.1186/1754-6834-3-10","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC2890632/","year":"2010","confidence":"high","comments":"\"Thygeson and co-workers compared four different analysis techniques involving XRD, and reported that the CI of Avicel cellulose varied significantly from 39% to 67%, depending on the technique used\"  — Cited literature range, illustrating method dependence for one material.  [Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK, 2010, confidence: high]"},{"id":509,"dataset":"cellulose","entity":"Avicel PH-101 microcrystalline cellulose","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"70.85","unit":"%","value_reported":"50-91.7","unit_reported":"%","method":"Review","method_detail":"Literature compilation of 18 measurements (XRD/NMR), reported in Cheah & Komiyama citing Park et al.","conditions":"Literature compilation of 18 measurements (XRD/NMR), reported in Cheah & Komiyama citing Park et al.","conditions_detail":"Literature compilation of 18 measurements (XRD/NMR), reported in Cheah & Komiyama citing Park et al. | measurement: XRD/NMR (various) | allomorph: I | source: Avicel PH-101","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Park et al [13] reports that in their literature compilation of 18 measurements, CrI of Avicel PH-101 reported varied from ca. 50 % to 91.7 %.\"  — Compilation range across 18 literature measurements.  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":510,"dataset":"cellulose","entity":"Avicel PH-101 microcrystalline cellulose","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"93.67","unit":"%","value_reported":"93.67","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: Avicel PH-101 (Sigma-Aldrich)","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Microcrystalline Cellulose 93.67 (Peak Height (Segal) Method)\"  — Figure 1; same MCC sample by four methods (Segal 93.67, Ruland-Vonk 63.06, Jayme-Knolle 95.44, deconvolution 53.51).  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":511,"dataset":"cellulose","entity":"Avicel PH-101 microcrystalline cellulose","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"63.06","unit":"%","value_reported":"63.06","unit_reported":"%","method":"Experiment","method_detail":"XRD, Ruland-Vonk two-peak area ratio method","conditions":"XRD, Ruland-Vonk two-peak area ratio method","conditions_detail":"XRD, Ruland-Vonk two-peak area ratio method | measurement: XRD Ruland-Vonk | allomorph: I | source: Avicel PH-101 (Sigma-Aldrich)","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Microcrystalline Cellulose 63.06 (Ruland-Vonk Method)\"  — Figure 1; Ruland-Vonk gave the lowest CrI among methods for this MCC.  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":512,"dataset":"cellulose","entity":"Avicel PH-101 microcrystalline cellulose","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"53.51","unit":"%","value_reported":"53.51","unit_reported":"%","method":"Experiment","method_detail":"XRD peak deconvolution","conditions":"XRD peak deconvolution","conditions_detail":"XRD peak deconvolution | measurement: XRD deconvolution | allomorph: I | source: Avicel PH-101 (Sigma-Aldrich)","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Microcrystalline Cellulose 53.51 (Deconvolution Method)\"  — Figure 1; deconvolution method for the same MCC.  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":513,"dataset":"cellulose","entity":"raw sugarcane bagasse cellulose","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"63.4","unit":"%","value_reported":"63.4","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: raw sugarcane bagasse (lignocellulose, ~43 wt% cellulose)","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Raw Sugarcane Bagasse ... 63.4 (Peak Height (Segal) Method)\"  — Figure 1; whole-biomass CrI (XRD intensity ratio), not pure cellulose. Ruland-Vonk 47.97, Jayme-Knolle 76.41, deconvolution 84.1 for same sample.  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":514,"dataset":"cellulose","entity":"raw palm kernel shell cellulose","entity_group":"cellulose (generic)","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"61.04","unit":"%","value_reported":"61.04","unit_reported":"%","method":"Experiment","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: raw palm kernel shell (lignocellulose, ~24 wt% cellulose)","doi":"10.21741/9781644902516-16","source_url":"https://www.mrforum.com/wp-content/uploads/open_access/9781644902516/16.pdf","year":"2023","confidence":"high","comments":"\"Raw Palm Kernel Shell ... 61.04 (Peak Height (Segal) Method)\"  — Figure 1; whole-biomass XRD intensity ratio; Ruland-Vonk 41.27 for same sample.  [Cheah YS, Komiyama M, 2023, confidence: high]"},{"id":515,"dataset":"cellulose","entity":"juniper cellulose","entity_group":"cellulose (generic)","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"36.0","unit":"%","value_reported":"34-38","unit_reported":"%","method":"Review","method_detail":"XRD Rietveld refinement","conditions":"XRD Rietveld refinement","conditions_detail":"XRD Rietveld refinement | measurement: XRD Rietveld | allomorph: I | source: juniper wood","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Juniper ... Rietveld 34-38%; Segal 19-22%; Peak Fitting 22-23%; Amorphous Subtraction 36%\"  — Chem Soc Rev methods-comparison; same juniper sample across four methods (Rietveld 34-38, Segal 19-22, peak fitting 22-23, amorphous subtraction 36).  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"},{"id":516,"dataset":"cellulose","entity":"juniper cellulose","entity_group":"cellulose (generic)","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"20.5","unit":"%","value_reported":"19-22","unit_reported":"%","method":"Review","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: juniper wood","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Juniper ... Segal 19-22%\"  — Note: for low-crystallinity wood, Segal here gives LOWER value than Rietveld - opposite of typical pure-cellulose ordering; method-dependence is sample-specific.  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"},{"id":517,"dataset":"cellulose","entity":"hemp cellulose","entity_group":"hemp","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"75.0","unit":"%","value_reported":"75","unit_reported":"%","method":"Review","method_detail":"XRD Rietveld refinement","conditions":"XRD Rietveld refinement","conditions_detail":"XRD Rietveld refinement | measurement: XRD Rietveld | allomorph: I | source: hemp fiber","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Hemp ... Rietveld 75%; Segal 40%; Peak Fitting 49%; Amorphous Subtraction 60%\"  — Same hemp sample: Rietveld 75, Segal 40, peak fitting 49, amorphous subtraction 60.  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"},{"id":518,"dataset":"cellulose","entity":"hemp cellulose","entity_group":"hemp","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"40.0","unit":"%","value_reported":"40","unit_reported":"%","method":"Review","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: hemp fiber","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Hemp ... Segal 40%\"  — Segal value for hemp; same sample as Rietveld 75% row.  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"},{"id":519,"dataset":"cellulose","entity":"nata de coco bacterial cellulose","entity_group":"bacterial cellulose","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"77.0","unit":"%","value_reported":"77","unit_reported":"%","method":"Review","method_detail":"XRD Rietveld refinement","conditions":"XRD Rietveld refinement","conditions_detail":"XRD Rietveld refinement | measurement: XRD Rietveld | allomorph: I | source: nata de coco (bacterial cellulose)","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Nata de coco ... Rietveld 77%; Segal 44-47%; Peak Fitting 49-52%; Amorphous Subtraction 61%\"  — Bacterial cellulose; same sample four methods (Rietveld 77, Segal 44-47, peak fitting 49-52, amorphous subtraction 61).  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"},{"id":520,"dataset":"cellulose","entity":"nata de coco bacterial cellulose","entity_group":"bacterial cellulose","entity_class":"native cellulose","property":"crystallinity index","property_key":"crystallinity_index","value":"45.5","unit":"%","value_reported":"44-47","unit_reported":"%","method":"Review","method_detail":"XRD, Segal peak-height method","conditions":"XRD, Segal peak-height method","conditions_detail":"XRD, Segal peak-height method | measurement: XRD peak height (Segal) | allomorph: I | source: nata de coco (bacterial cellulose)","doi":"10.1039/D2CS00569G","source_url":"https://pubs.rsc.org/en/content/articlehtml/2023/cs/d2cs00569g","year":"2023","confidence":"high","comments":"\"Nata de coco ... Segal 44-47%\"  — Segal value for the bacterial-cellulose sample.  [Salem KS, Kasera NK, Rahman MA, Jameel H, et al., 2023, confidence: high]"}]}