{"count":839,"next":"http://glycodata.org/api/gdd/glyco-properties/?format=json&page=18","previous":"http://glycodata.org/api/gdd/glyco-properties/?format=json&page=16","results":[{"id":321,"dataset":"cellulose","entity":"microcrystalline cellulose MCC-C (acid hydrolysis 140 C, OPEFB)","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"220.0","unit":"C","value_reported":"220","unit_reported":"C","method":"Experiment","method_detail":"TGA, onset (Tonset), N2, 10 C/min","conditions":"TGA, onset (Tonset), N2, 10 C/min","conditions_detail":"TGA, onset (Tonset), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I/II | crystallinity (%): 60.64","doi":"10.17576/mjas-2016-2005-17","source_url":"https://www.ukm.my/mjas/v20_n5/pdf/FatinAfifah_20_5_17.pdf","year":"2016","confidence":"high","comments":"\"Table 2: MCCC Tonset 220 C, Tmax 350 C\"  — Table 2. Higher hydrolysis temperature lowered Tonset/Tmax.  [Ahmad Kuthi FA, Norazli NRA, Badri KH, 2016, confidence: high]"},{"id":322,"dataset":"cellulose","entity":"microcrystalline cellulose MCC-C (acid hydrolysis 140 C, OPEFB)","entity_group":"microcrystalline cellulose (MCC)","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"350.0","unit":"C","value_reported":"350","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min","conditions":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I/II | crystallinity (%): 60.64","doi":"10.17576/mjas-2016-2005-17","source_url":"https://www.ukm.my/mjas/v20_n5/pdf/FatinAfifah_20_5_17.pdf","year":"2016","confidence":"high","comments":"\"Table 2: MCCC Tonset 220 C, Tmax 350 C\"  — Table 2.  [Ahmad Kuthi FA, Norazli NRA, Badri KH, 2016, confidence: high]"},{"id":323,"dataset":"cellulose","entity":"commercial microcrystalline cellulose (CMCC, Sigma-Aldrich)","entity_group":"carboxymethyl cellulose (CMC)","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"295.0","unit":"C","value_reported":"295","unit_reported":"C","method":"Experiment","method_detail":"TGA, onset (Tonset), N2, 10 C/min","conditions":"TGA, onset (Tonset), N2, 10 C/min","conditions_detail":"TGA, onset (Tonset), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I | crystallinity (%): 76.19","doi":"10.17576/mjas-2016-2005-17","source_url":"https://www.ukm.my/mjas/v20_n5/pdf/FatinAfifah_20_5_17.pdf","year":"2016","confidence":"high","comments":"\"The high onset temperature was observed in CMCC (295 C) was due to its high percentage of crystallinity\"  — Commercial reference MCC; CrI 76.19%. Tmax 345 C (Table 2).  [Ahmad Kuthi FA, Norazli NRA, Badri KH, 2016, confidence: high]"},{"id":324,"dataset":"cellulose","entity":"commercial microcrystalline cellulose (CMCC, Sigma-Aldrich)","entity_group":"carboxymethyl cellulose (CMC)","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"345.0","unit":"C","value_reported":"345","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min","conditions":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (maximum degradation), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I | crystallinity (%): 76.19","doi":"10.17576/mjas-2016-2005-17","source_url":"https://www.ukm.my/mjas/v20_n5/pdf/FatinAfifah_20_5_17.pdf","year":"2016","confidence":"high","comments":"\"Table 2: CMCC Tonset 295 C, Tmax 345 C\"  — Table 2.  [Ahmad Kuthi FA, Norazli NRA, Badri KH, 2016, confidence: high]"},{"id":325,"dataset":"cellulose","entity":"cellulose (high-purity micro-granular powder, Sigma-Aldrich)","entity_group":"cellulose (generic)","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"226.0","unit":"C","value_reported":"226","unit_reported":"C","method":"Experiment","method_detail":"TGA, critical temperature Tc (minimum temperature for degradation), non-oxidizing/N2, multiple rates 2.5-40 C/min","conditions":"TGA, critical temperature Tc (minimum temperature for degradation), non-oxidizing/N2, multiple rates 2.5-40 C/min","conditions_detail":"TGA, critical temperature Tc (minimum temperature for degradation), non-oxidizing/N2, multiple rates 2.5-40 C/min | atmosphere: N2","doi":"","source_url":"https://bioresources.cnr.ncsu.edu/resources/kinetics-of-thermal-degradation-of-cellulose-analysis-based-on-isothermal-and-linear-heating-data/","year":"2016","confidence":"medium","comments":"\"the critical temperature, approximately 226 C, represented the minimum temperature for the degradation process\"  — Tc is a kinetic minimum-onset, not a peak. BioResources 11(3):5870-5888.  [Lopez-Beceiro J, Alvarez-Garcia A, Sebio-Punal T, Zaragoza-Fernandez S, Alvarez-Garcia B, Diaz-Diaz A, Janeiro J, Artiaga R, 2016, confidence: medium]"},{"id":326,"dataset":"cellulose","entity":"Eucalyptus grandis wood cellulose fiber","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"364.0","unit":"C","value_reported":"364","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"a second weight loss occurs at around 350 C, due to the main degradation of cellulose (Table 5: Eucalyptus grandis DTG peak 364 C, Ti 250 C)\"  — From summary Table 5. Ti (3% wt loss) 250 C.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":327,"dataset":"cellulose","entity":"Eucalyptus grandis wood cellulose fiber","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"250.0","unit":"C","value_reported":"250","unit_reported":"C","method":"Experiment","method_detail":"TGA, onset Ti (3% mass loss), N2, 10 C/min","conditions":"TGA, onset Ti (3% mass loss), N2, 10 C/min","conditions_detail":"TGA, onset Ti (3% mass loss), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | mass-loss basis (%): 3 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Eucalyptus grandis Ti (3% wt loss) 250 C, DTG peak 364 C\"  — Ti defined as 3% mass loss temperature.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":328,"dataset":"cellulose","entity":"Pinus elliottii wood cellulose fiber","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"367.0","unit":"C","value_reported":"367","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Pinus elliottii Ti 251 C, DTG peak 367 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":329,"dataset":"cellulose","entity":"Dipteryx odorata wood cellulose fiber","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"368.0","unit":"C","value_reported":"368","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Dipteryx odorata Ti 257 C, DTG peak 368 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":330,"dataset":"cellulose","entity":"Mezilaurus itauba wood cellulose fiber","entity_group":"dissolving/wood pulp","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"350.0","unit":"C","value_reported":"350","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Mezilaurus itauba Ti 237 C, DTG peak 350 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":331,"dataset":"cellulose","entity":"Curaua fiber cellulose","entity_group":"cellulose (generic)","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"344.0","unit":"C","value_reported":"344","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Curaua Ti 260 C, DTG peak 344 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":332,"dataset":"cellulose","entity":"Jute fiber cellulose","entity_group":"jute","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"365.0","unit":"C","value_reported":"365","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Jute Ti 262 C, DTG peak 365 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":333,"dataset":"cellulose","entity":"Kenaf fiber cellulose","entity_group":"kenaf","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"364.0","unit":"C","value_reported":"364","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Kenaf Ti 238 C, DTG peak 364 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":334,"dataset":"cellulose","entity":"Ramie fiber cellulose","entity_group":"ramie","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"357.0","unit":"C","value_reported":"357","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Ramie Ti 221 C, DTG peak 357 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":335,"dataset":"cellulose","entity":"Sisal fiber cellulose","entity_group":"sisal","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"347.0","unit":"C","value_reported":"347","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Sisal Ti 209 C, DTG peak 347 C\"  — From summary Table 5.  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":336,"dataset":"cellulose","entity":"Buriti fiber cellulose","entity_group":"cellulose (generic)","entity_class":"native cellulose","property":"thermal degradation temperature","property_key":"Td","value":"334.0","unit":"C","value_reported":"334","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min","conditions_detail":"TGA/DTG, Tmax (DTG peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10 | allomorph: I","doi":"10.3390/ma7096105","source_url":"https://pmc.ncbi.nlm.nih.gov/articles/PMC5456159/","year":"2014","confidence":"high","comments":"\"Table 5: Buriti DTG peak 334 C\"  — From summary Table 5; lowest DTG peak among fibers studied (high extractive content).  [Poletto M, Ornaghi Junior HL, Zattera AJ, 2014, confidence: high]"},{"id":337,"dataset":"cellulose","entity":"cellulose (sugarcane bagasse alpha-cellulose)","entity_group":"dissolving/wood pulp","entity_class":"pulp / microcrystalline cellulose","property":"thermal degradation temperature","property_key":"Td","value":"353.0","unit":"C","value_reported":"353","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10","doi":"","source_url":"https://www.cellulosechemtechnol.ro/pdf/CCT7-8(2019)/p.667-675.pdf","year":"2019","confidence":"high","comments":"\"the main decomposition stage at 353, 295 and 330 C ... for cellulose, CMC and CMCA, respectively\"  — Cellulose Chem. Technol. 53(7-8):667-675. Table 1: cellulose step2 = 353 C. alpha-cellulose 94.2% from bagasse pulp.  [El-Sakhawy M, Tohamy HS, Salama A, Kamel S, 2019, confidence: high]"},{"id":338,"dataset":"cellulose","entity":"carboxymethyl cellulose (CMC, DS 0.45)","entity_group":"carboxymethyl cellulose (CMC)","entity_class":"cellulose derivative","property":"thermal degradation temperature","property_key":"Td","value":"295.0","unit":"C","value_reported":"295","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10","doi":"","source_url":"https://www.cellulosechemtechnol.ro/pdf/CCT7-8(2019)/p.667-675.pdf","year":"2019","confidence":"high","comments":"\"the main weight loss of CMC (295 C) was shifted to lower temperature than that of cellulose (353 C), which may confirm the lower thermal stability of CMC\"  — CMC DS 0.45. Table 1 step 2 = 295 C.  [El-Sakhawy M, Tohamy HS, Salama A, Kamel S, 2019, confidence: high]"},{"id":339,"dataset":"cellulose","entity":"carboxymethyl cellulose acetate (CMCA)","entity_group":"cellulose acetate","entity_class":"cellulose derivative","property":"thermal degradation temperature","property_key":"Td","value":"330.0","unit":"C","value_reported":"330","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (main decomposition stage, DTA peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10","doi":"","source_url":"https://www.cellulosechemtechnol.ro/pdf/CCT7-8(2019)/p.667-675.pdf","year":"2019","confidence":"high","comments":"\"the main decomposition stage at 353, 295 and 330 C ... for cellulose, CMC and CMCA, respectively\"  — Table 1 step 2 = 330 C.  [El-Sakhawy M, Tohamy HS, Salama A, Kamel S, 2019, confidence: high]"},{"id":340,"dataset":"cellulose","entity":"carboxymethyl cellulose acetate butyrate (CMCAB)","entity_group":"cellulose acetate","entity_class":"cellulose derivative","property":"thermal degradation temperature","property_key":"Td","value":"358.0","unit":"C","value_reported":"358","unit_reported":"C","method":"Experiment","method_detail":"TGA/DTA, Tmax (maximum degradation rate step / DTA peak), N2, 10 C/min","conditions":"TGA/DTA, Tmax (maximum degradation rate step / DTA peak), N2, 10 C/min","conditions_detail":"TGA/DTA, Tmax (maximum degradation rate step / DTA peak), N2, 10 C/min | atmosphere: N2 | heating rate (K/min): 10","doi":"","source_url":"https://www.cellulosechemtechnol.ro/pdf/CCT7-8(2019)/p.667-675.pdf","year":"2019","confidence":"high","comments":"\"The third decomposition step between 310-600 C represented the maximum degradation rate event at 357 C ... an endothermic reaction at 357 C for CMCAB (Table 1 step 3 = 358 C)\"  — Table 1 step 3 = 358 C (text DTA peak 357 C). CMCAB more stable than cellulose.  [El-Sakhawy M, Tohamy HS, Salama A, Kamel S, 2019, confidence: high]"}]}